Which of the following statements about the electron is incorrect?
The energy of electron in first energy level is -21.79 × 10-12erg per atom. The energy of electron in second energy level is:
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Solution
Zeeman effect refers to the :
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Solution
Zeeman effect refers to splitting of lines of an emission spectrum in magnetic field.
Correct set of four quantum numbers for valence electron of rubidium (Z = 37) is
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Solution
Identify the correct statement:
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Solution
Those orbitals which are equal in energies are called degenerate orbitals. All sp3 orbitals are degenerate as these are equal in energies.
The first emission line of hydrogen atomic spectrum in the Balmer series appears is (R = Rydberg constant)
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Solution
\(\Delta E = R \left( \frac{1}{n_{1}^{2}} - \frac{1}{n_{2}^{2}} \right)\)
First line in Balmer series results in the transition : n2 = 3 to n2 = 2.
Pick out the isoelectronic structure from the following:
(i) \(\overset{+}{C}H_{3}\)
(ii) \(H_{3}\overset{+}{O}\)
(iii) \(NH_{3}\)
(iv) \(\overset{-}{C}H_{3}\)
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Solution
(i) \(\overset{+}{C}H_{3}\) 8 electrons
(ii) \(H_{3}\overset{+}{O}\) 10 electrons
(iii) \(NH_{3}\) 10 electrons
(iv) \(\overset{-}{C}H_{3}\) 10 electrons
The allowed values of m for 1 = 2 is
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Solution
For every l, quantum number 'm' can take values from –l to+l. So for l = 2, m = –2, –1, 0, +1, +2
Which of the following transitions of electrons in the hydrogen atom will emit maximum energy ?
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Solution
ΔE for two energy levels \(21.79 \left( \frac{1}{n_{1}^{2}} - \frac{1}{n_{2}^{2}} \right)\) J/atom
According to Bohr’s theory,the angular momentum of an electron in 5th orbit is
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Solution
Angular momentum of an electron in nth orbit is given by
mvr = nh⁄2π
For n = 5, we have
Angular momentum of electron = 5h⁄2π = 2.5h⁄2π